Head study of a woman, very likely Georgiana Burne-Jones, the artist's wife, as the features are strikingly similar to portraits of her, both by Burne-Jones himself, and her brother-in-law, Edward Poynter. This may be a head study for 'The Annunciation' (Lady Lever Art Gallery, Port Sunlight); some scholars believe the Virgin's face is modelled on Georgiana (see 'Edward Burne-Jones: Victorian Artist-Dreamer', pages 240-241). The dates of 'The Annunciation' correspond with the dates of this sketchbook, so it is plausible to make such an identification.
An unusual drawing of Georgiana, revealing something of her emotional state having gone through the testing experience of the Zambaco affair, it is rare for Burne-Jones to allow himself such an emotional release and shows an almost unique insight into their relationship. The other portraits of his wife tend to gloss over any emotion and record Georgiana's impassive stare.